Surface Chemical Structure and Morphological Analysis of Fallen Teak Leaves (Tectona grandis) Powder for Methylene Blue Adsorption

Dwi Ima Hikmawati, Embun Rachma Haqiqi

Abstract


In recent year, the research focus has been shifted toward developing of an environmentally friendly system to eliminate any pollutants from Waste. The potential of fallen teak leaves powder for removal of methylene blue has been succesfully carried out by batch adsorption system. The purpose of this study is to characterize an adsorbent obtained from local fallen teak leaves. The characterization focused on the surface of chemical structure analysis obtained from Fourier Transform Infrared (FTIR) spectroscopy and morphological analysis by Scanning Electron Microscopy (SEM) in order to get an idea fuctional group as active site and textural properties. The FTIR results have explaned the presence of some functional groups such as –OH, C=C, COO, CO, NO2 on FTLP surface that could be potential adsorption sites for interaction with MB molecules. The SEM photographs morphology of FTLP surface has a rough surface with almost more non-uniform.



Keywords


chemical structure analysis, environmentally friendly adsorbent, fallen teak leaves, methylene blue, morphological analysis

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Bello, O. S., Adegoke, K. A., & Akinyunni, O. O. (2017). Preparation and Characterization of a Novel Adsorbent from Moringa oleifera Leaf. Appl Water Sci, 7, 1295-1305.

Bello, O. S. & Semire, B. (2012). Equilibrium, Kinetic, and Quantum Chemical Studies on the Adsorption of Congo Red using Imperata cylindrica Leaf Powder Activated Carbon. Toxicol Environ Chem, 94, 1114–1124

Dávila-Jiménez, M. M., Elizalde-González, M. P., & Peláez-Cid, A. A. (2005). Adsorption Interaction between Natural Adsorbents and Textile Dyes in Aqueous Solution. Colloids and Surfaces A: Physicochem Eng. Aspects, 254, 107-114.

Dwivedi, N., Balomajumder, C., & Mondal, P. 2016. Comparative investigation on the removal of cyanide from aqueous solution using two different bioadsorbents, Water Resources and Industry, 28-40.

Gadd, G. M. 2009. Biosorption: Critical Review of Scientific Rationale, Environmental Importance and Significance for Pollution Treatment. J. Chem. Technol. Biotechnol, 84, 13-28.

Haqiqi, E. R. (2018). Studi Awal Kemampuan Adsorpsi Komposit Kulit Telur Ayam dengan Sekam Padi sebagai Adsorben Metil Orange. Cheesa, 1(1), 15-20.

Hikmawati, D. I. (2018). Preparasi Serbuk Guguran Daun Jati (Tectona grandis) Kering dan Aplikasinya sebagai Adsorben Metilen Biru dengan Sistem Batch. Prosiding Seminar Nasional Teknik Kimia Soebardjo Brotohardjono XIV, Tanggal 04 Juli 2018. Surabaya: Universitas Pembangunan “Veteran” Jawa Timur. (a)

Hikmawati, D. I. (2018). Studi Perbandingan Kinerja Serbuk dan Arang Biji Salak Pondoh (Salacca zalacca) pada Adsorpsi Metilen Biru. Chimica et Natura Acta, 6(2), 2018. (b)

Jafar, A. A. & Balasubramanian, S. (2010). Adsorption of Pb(II) Ion on Teak Leaves Activated Carbon: A Kinetic and Equilibrium Study, Der Chemica Sinica, 1(2), 35-43.

King, P., Srinivas, P., Kumar, Y. P., Prasad, V. S. R. K. (2006). Sorption of copper(II) ion from aqueous solution by Tectona grandis l.f. (teak leaves powder). Journal of Hazardous Materials, B136: (2006) 560–566.

Mishra, Y., Sowmya, V., & Shanthakumar, S. (2015). Adsorption Studies of Basic Dyes onto Teak (Tectona grandis) Leaf Powder. JUEE, 9(2), 102-108.

Okada, K., Yamamoto, N., Kameshima, Y., & Yasumori, A. (2003). Adsorption Properties of Activated Carbon from Waste Newspaper Prepared by Chemical and Physical Activation. J. Colloid Interface Sci., 262, 194-199.

Prachpreecha, O., Pipatpanyanugoon, K., & Sawangwong. (2016). A Study of Characterizations and Efficiency of Actived Carbon Prepared from Peel and Bunch of Banana for Methyl Orange DyeAdsorption. Journal of Environmental Science, Toxicology and Food Technology, 10(4), 17-26.

Rajendiren, S. V., Soupramaniane, G., & Sugumar. (2017). Studies on Teak Leaves (Tectona grandis) as Low-cost Adsorbent for the Treatment of Detergent Industrial Waste Water. International Journal of Scientific Engineering and Research, 5(5), 110-115.

Shrestha, S. (2016). Chemical, Structural, and Elemental Characterization of Biosorbents Using FE-SEM, SEM-EDX, XRD/XPRD, and ATR-FTIR Technique, J Chem Eng Process Technol, 7(3), 1-11.

Tsai, W-T., Hsu, H-C., Su, T-Y., Lin, K-Y., Lin, C-M. (2008). Removal of Basic Dye (Methylene Blue) from Waste Waters Utilizing Beer Brewery Waste. J. Hazard. Mater. 154, 73-78.

Vilvanathan S, & Shanthakumar, S. (2016) Removal of Ni(II) and Co(II) ions from aqueous solution using teak (Tectona grandis) leaves powder: adsorption kinetics, equilibrium and thermodynamics study, Desalination and Water Treatment, 57, 3995-4007.


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DOI: http://doi.org/10.25273/cheesa.v2i1.4334

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