Influence of Chicken EggShell Powder Ratio with Coarse Rice Husk on Methyl Orange Removal from Aqueous Solution

Embun Rachma Haqiqi, Dwi Ima Hikmawati

Abstract


Chicken eggshell and rice husk waste have been succesfully used as a potential adsorbent of methyl orange (MO). In this study, after the washing and drying process, chicken eggshells  were mashed while the rice husk was left intact. Chicken eggshell powder and coarse rice husk were combined and varied its composition ratio by 3: 1, 2: 1, 1: 1, 1: 2, and 1: 3. The adsorption process of 50 mL MO 20 ppm in aqueous solution with 11 grams of adsorbent was measured using the UV-Vis Spectrophotometer Genesys 20 at 465 nm. Based on the results of the study, the adsorbent with a variation of 1: 1 in ratio was able to adsorb MO from the solution up to 27.70% within 60 minutes.


Keywords


Adsorbtion; chicken eggshell; low-cost adsorbent; methyl orange; rice husk

Full Text:

DOWNLOAD PDF

References


Apriliani, A. (2010). Pemanfaatan Arang Ampas Tebu sebagai Adsorben Ion Logam Cd, Cr, Cu, dan Pb dalam Air Limbah. Skripsi. Fakultas Sainstek UIN Syarif Hidayatullah Jakarta.

Badriyah, L. & Putri, M. P. (2017). Kinetika adsorpsi Cangkang Telur pada Zat Warna Metilen Biru. Journal of Chemistry, 5(3), 85-91.

Bamroongwongdee, C., Gaewkhem, S., & Siritrakul, P. (2018). Kinetics, Equilibrium, and Thermodynamics of Methyl Orange Adsorption onto Modified Rice Husk. KMUTNB Int. J. Appl. Sci. Technol., 11(3), 185-197.

Belay, K. & Hayelom, A. (2014). Removal of Methyl Orange from Aqueous Solutions Using Thermally Treated Egg Shell (Locally Available and Low Cost Biosorbent). Chemistry and Materials Research, 6(7), 31-39.

Carvalho, J., Araujo, J., & Castro, F. (2011). Alternative Low-cost Adsorbent for Water and Wastewater Decontamination Derived from Eggshell Waste: An overview. Waste Biomass Valor, 2, 157-167.

Chen, S., Zhang, J., Zhang, C., Yue, Q., Li, Y., & Li, E. (2010). Equilibrum and kinetic studies of methyl orange and methyl violet adsorption on activated carbon derived from Phragmites australis. Desalination, 252, 149-156.

Chowdhury, S., Mishra, R., Saha, P., & Kushwaha, P. (2011). Adsorption thermodynamics, kinetics, and isosteric heat of adsorption of malachite green onto chemically modified rice husk. Desalination, 265(1-3), 159-168.

Daraei, H., Mittal, A., Noorisepehr, M., & Mittal, J. (2013). Separation of chromium from water samples using eggshell powder as a low-cost sorbent: kinetic and thermodynamic studies. Desalination and Water Treatment. Hal. 1-7.

Diapati. M. (2009). Ampas Tebu Sebagai Adsorben Zat Warna Reaktif Cibacron Red. Skripsi. FMIPA, Kimia IPB.

Egwuonwu, P. D. I. M. (2013). Adsorption of Methyl Red and Methyl Orange Using Different Tree Bark Powder. Academic Research International, 4(1), 330-338.

Haqiqi, E. R. (2018). Analisis FTIR (Fourier Transform InfraRed) Adsorben Metil Orange dari Limbah Cangkang Telur Ayam Dikombinasi Biomassa Sekam Padi: Variasi Ukuran Sekam Padi. Proceeding Seminar Nasional SOEBARDJO BROTOHARDJONO XIV. (a)

Haqiqi, E. R. (2018). Analisis FTIR (Fourier Transform Infrared) Adsorben Zat Warna dari Limbah Cangkang Telur Ayam Dikombinasi Biomassa Sekam Padi. Seminar Nasional Kimia, 17-25. (b)

Haqiqi, E. R. (2018). Studi Awal Kemampuan Adsorpsi Komposit Kulit Telur Ayam dengan Sekam Padi sebagai Adsorben Metil Orange. Cheesa. 1(1), 15-20. (c)

Hassan, A. A. & Abdulhussein, H. A. (2015). Methyl Red Dye Removal from Aqueous Solution by Adsorption on Rice Hulls. Journal of Babylon University, Engineering Sciences, 2(23), 1-12.

Fitriyana & Safitri, E. (2015). Pemanfaatan Cangkang Telur Ayam Sebagai Adsorben Untuk Meningkatkan Kualitas Minyak Jelantah. Konversi. 4(1), 12-16.

Karaςetin, G., Sivrikaya, S., & Imamoǧlu, M. (2014). Adsorption of methylene blue from aqueous solutions by activated carbon prepared from hazelnut husk using zinc chloride. Journal of Analytical and Applied Pyrolysis, 110, 270-276.

Koumanova, B., Peeva, P., Allen, S. J., Gallagher, K. A., & Healy, M. G. (2002). Biosorption from aqueous solution by egg shell membranes and Rhizopus oryzae: Equilibrium and kinetic studies. J. Chem. Technol. Biotechnol. 77, 539-545.

Lafi R. & Hafiane, A. 2016. Removal of methyl orange (MO) from aqueous solution using cationic surfactans modified coffe waste (MCWs). Journal of the Taiwan Institute of Chemical Engineers, 58, 424-433.

Leiva, P., Ciannamea, E., Ruseckaite, R. A., & Stefani, P. M. (2007). Medium-density particleboards from rice husks and soybean protein concentrate. Journal of Applied Polymer Science, 106(2), 1301-1306.

Ludueña, L., Fasce, D., Alvarez, V. A., & Stefani, P. M. (2011). Nanocellulose from rice husk following alkaline treatment to remove silica. BioResources, 6(2), 1440-1453.

Mahatmanti, F. W. & Sumarni, W. (2003). Kajian Termodinamika Penyerapan Zat Warna Indikator Metil Oranye (MO) Dalam Larutan Air Oleh Adsorben Kitosan. JSKA, VI(2), 1-19.

Mittal, A., Malviya, A., Kaur, D., Mittal, J., & Kurup, L. (2007). Studies on the adsorption kinetics and isotherms for the removal and recovery of Methyl Orange from wastewaters using waste materials. 148, 229-240.

Nurlaili, T., Kurniasari, L., & Ratnani, R. D. (2017). Pemanfaatan Limbah Cangkang Telur Ayam Sebagai Adsorben Zat Warna Methyl Orange Dalam Larutan. Inovasi Teknik Kimia, 2(2), 11-14.

Pramanpol, N., & Nitayapat, N. (2006). Adsorption of reactive dye by eggshell and its membrane. Kasetsat J.: Nat. Sci. 40, 192-197.

Purbaningtias, T. E., Wiyantoko, B., Kurniawati, P., & Ruwindya, Y. 2015. Removal of Methyl Orange in Aqueous Solution using Rice Husk. The 1st International Seminar on Chemical Education 2015, 241-246.

Purnama, H. & Kurnianto, A. R. (2016). Pemanfaatan Tongkol Jagung Untuk Adsorpsi Zat Warna Reactive Blue 19. The 3rdUniversty Research Coloquium. Hal. 41-47.

Rahayu, A. N. & Adhitiyawarman. (2014). Pemanfaatan Tongkol Jagung Sebagai Adsorben Besi Pada Air Tanah. JKK, 3(3), 7-13.

Saha, T. K. (2010). Adsorption of methyl orange onto chitosan from aqueous solution. Journal of Water Resource and Protection, 2(10), 898-906.

Salman, D. D., Ulaiwi, W. S., & Tariq, N. M. (2012). Determination of the Optimal Conditions of Methylene Blue Adsorption by the Chicken Egg Shell Membrane. International Journal of Poultry Science. 11(6), 391-396.

Sanredina, Irianty, R. S., & Yelida. (2017). Pengaruh Massa Adsorben terhadap Adsorpsi Pergasol Red dengan Proses Batch Menggunakan Cangkang Kulit Telur Terkalsinasi. Jom FTEKNIK, 4(1), 1-4.

Sejie, F. P. & Nadiye-Tabbiruka, M. S. (2016). Removal of Methyl Orange (MO) from Water by adsorption onto Modified Local Clay (Kaolinite). Physical Chemistry. 6(2), 39-48.

Sharma, P., Kaur, R., Baskar, C., & Chung, W. J. (2010) Removal of methylene blue from aqueous waste using rice husk and rice husk ash. Desalination, 259(1-3), 249-257.

Subbaiah, M. V. & Kim, D-S. (2016). Adsorption of methyl orange from aqueous solution by aminated pumpkin seed powder: Kinetics, isotherms, and thermodynamic studies. Ecotoxicology and Environmental Safety. 128, 109–117.

Susanto, T. N., Atmono, & Natalina. (2017). Pemanfaatan Limbah Cangkang Telur Ayam Sebagai Media Adsorben Dalam Penurunan Kadar Logam Kromium Heksavalen (Cr6+) Pada Limbah Cair Industri Elektroplating. Ecolab, 11(1), 1–52.

Sutiyani, F. & Sukarnen. (2015). Uji Efektivitas Pemanfaatan Limbah Ampas Tebu Dan Serbuk Kayu Sebagai Adsorben Untuk Pengolahan Air Limbah Pewarnaan Jeans. Seminar Nasional Sains dan Teknologi Terapan III. Hal. 663-670.

Tarley, C. R & Arruda, M. A. (2004). Biosorption of heavy metals using rice milling by-products, Characterisation and application for removal of metals from aqueous effluents. Chemosphere. 54(7), 987-95.

Tsai, W. T., Yang, J. M., Lai, C. W., Cheng, Y. H., Lin, C. C., & Yeh, C. W. (2006). Characterization and adsorption properties of eggshells and eggshell membrane. Bioresource Technology, 97(3), 488-493.

Wardalia. (2016). Karakterisasi Pembuatan Adsorben Dari Sekam Padi Sebagai Pengadsorp Logam Timbal Pada Limbah Cair. Jurnal Integrasi Proses, 6(2), 83–88.

Widjajanti, E. (2009). Kajian Penggunaan Adsorben Sebagai Alternatif Pengolahan Limbah Zat Pewarna Tekstil. Proseding Seminar Nasional Kimia.

Widjajanti, E., Regina, T. P., & Utomo, M. P. (2011). Pola Adsorpsi Zeolit Terhadap Pewarna Azo Metil Merah Dan Metil Jingga. Jurusan Pendidikan Kimia, FMIPA, Universitas Negeri Yogyakarta.

Yagub, M. T., Sen, T. K., Afroze, S., & Ang, H. M. (2014). Dye and its removal from aqueous solution by adsorption: A review. Advances in Colloid and Interface Science, 209, 172-184.

Zhao, P., Zhang, R., & Wang, J. (2017). Adsorption of methyl orange from aqueous solution using chitosan/diatomite composite. Water and Science Technology, In Press. Hal. 1-10.

Zulfikar, M. A., Novita, E., Hertadi, R., & Djajanti, S. D. (2013). Removal of humid acid from peat water using untreated powdered eggshell as a low cost adsorbent. Int. J. Environ. Sci. Technol., 10, 1357-1366.


Article Metrics

Abstract has been read : 1117 times
DOWNLOAD PDF file viewed/downloaded: 0 times


DOI: http://doi.org/10.25273/cheesa.v2i1.4335

Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

Accredited:
   
Indexed by:
         

        

                                                         

                                                                                     Creative Commons License

Chemical Engineering Research Articles by http://e-journal.unipma.ac.id/index.php/cheesa is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
                                                                                         
Copyright of CHEESA: Chemical Engineering Research Articles, ISSN 2614-8757 (Print)2615-2347 (Online)
Published by Universitas PGRI Madiun
  
Web Analytics View Statistic